Optiphen
INCI: Phenoxyethanol (and) Caprylyl Glycol
A paraben- and formaldehyde-free broad-spectrum preservative blend. Phenoxyethanol for bacteria, caprylyl glycol for mould and yeast.
Overview
Optiphen is a pre-mixed preservative blend. It is a clear, slightly oily liquid that combines two ingredients: phenoxyethanol (the bacteria killer) and caprylyl glycol (which handles moulds and yeasts and also acts as a humectant). One bottle, full broad-spectrum coverage, no maths.
For a hobbyist, this is one of the easiest preservatives to fall in love with. You measure out roughly 1% of your total formula, drop it in during the cool-down phase, and walk away. There is no pH-strip drama like with Cosgard, no formaldehyde-release concerns like with Liquid Germall Plus, and no need to layer two products. It is a good “next step” preservative for someone who has outgrown neat phenoxyethanol and wants something with stronger fungal protection in a single bottle.
Optiphen sits in the middle of the price/performance scale — pricier than neat phenoxyethanol, much cheaper than the Ecocert-certified naturals, and effective in nearly every formula that sits at skin-friendly pH.
What it does in a formula
Primary role: broad-spectrum preservation. The phenoxyethanol portion handles bacteria. The caprylyl glycol portion handles fungi (mould and yeast). Together they cover the full microbial spectrum that water-based cosmetics actually face.
Secondary roles: the caprylyl glycol is also a mild humectant and skin-feel enhancer — it does not feel like a preservative on the skin, more like a glycol moisturiser. It can also boost the activity of other preservatives, which is part of why this combo works at relatively low total percentages.
How to use
Use at 0.75-1.5% of the total formula. 1% is the standard starting point and the safe default for most hobbyist recipes.
Add to the cool-down phase. Optiphen tolerates heat up to about 80°C, which is unusually heat-stable for a preservative, but there is no benefit to heating it — and the rest of the cool-down phase ingredients (fragrance, panthenol, actives) are heat-sensitive anyway, so just keep them all together at the end.
Optiphen works in pH 4-8, with optimal performance between 4 and 6. This covers almost every leave-on skincare formula (which sits at pH 4.5-5.5) and most shower products. It will not work in high-pH solid soaps or cold-process bar soap.
Solubility quirk: Optiphen is only sparingly water-soluble — roughly 1.2% in water. If you add it to a very watery formula (a toner, a hydrosol-based mist, a thin serum) it can cause cloudiness or even separate. For these, dissolve it first in a small amount of warm oil or glycol, or switch to a fully water-soluble alternative like Liquid Germall Plus.
It can also thin out emulsions slightly — if a lotion that was thick suddenly turns runny when you add the preservative, this is why. You can compensate with a touch more thickener.
Best for / Worst for
Best for: lotions, creams, conditioners, shower gels, masks, leave-on emulsions of any kind. The default preservative for most “real” skincare recipes a hobbyist will tackle.
Worst for: very watery serums and toners (will cause cloudiness — use Liquid Germall Plus or Geogard 221 instead). Also not suitable for high-pH formulas like solid shampoo bars sitting above pH 8, cold-process soap, or hair-removal creams.
Common pitfalls
Cloudiness in thin formulas: by far the most common Optiphen complaint. It is a solubility issue, not a preservation failure. Either solubilise it (a small amount of polysorbate 20) or switch preservatives.
Emulsion thinning: as noted above, Optiphen can soften emulsions. Add a little more emulsifier or a co-thickener if your lotion feels runnier than expected.
Using it in high-pH formulas: Optiphen loses efficacy above pH 8. If you are making a high-pH product (rare in DIY, but it happens), you need a different system.
Confusing it with Optiphen Plus: Optiphen and Optiphen Plus are different products. Optiphen Plus adds sorbic acid and works down to lower pH — useful if you are making very acidic formulas. They are not interchangeable.
Substitutes
- Phenoxyethanol (neat) + a separate antifungal — same active ingredient as in Optiphen, plus the partner of your choice. Cheaper but two bottles instead of one.
- Euxyl PE 9010 — phenoxyethanol with ethylhexylglycerin (instead of caprylyl glycol). Very similar performance, slightly different skin feel, popular in EU formulations.
- Liquid Germall Plus — covers bacteria, yeast, and mould at 0.1-0.5%. Fully water-soluble, no cloudiness in serums. Releases trace formaldehyde though, which some customers want to avoid.
- Geogard ECT — Ecocert-certified natural alternative. Use this if you specifically need the “natural” label, otherwise Optiphen is easier to formulate with.